Dimethylamine Borane Neurotoxicity

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Axonal polyneuropathy after acute dimethylamine borane intoxication.

OBJECTIVE To study a patient with axonal polyneuropathy due to acute dimethylamine borane (DMAB) intoxication. PATIENT Confusion and drowsiness in the acute stage, followed by cognitive impairments and polyneuropathy, are reported in a chemical factory worker after acute exposure to DMAB. RESULTS Nerve conduction studies indicated axonal polyneuropathy, particularly in the motor nerves. Sur...

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Case Report: The Clinical Toxicity of Dimethylamine Borane

CONTEXT Dimethylamine borane (DMAB) is a reducing agent used in nonelectric plating of semiconductors. Exposures are usually through occupational contact. We report here four cases of people who suffered from work-related exposure to DMAB. CASE PRESENTATION Three patients exposed to DMAB decontaminated immediately by drinking a lot of water; they reported dizziness, nausea, diarrhea 6-8 hr la...

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Dehydrocoupling of dimethylamine-borane catalysed by rhenium complexes and its application in olefin transfer-hydrogenations.

Re(I) complexes are applied as catalysts for the dehydro-coupling of Me2NH.BH3 and the transfer-hydrogenation of olefins.

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Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds.

Dehydrogenation of Me(2)NH·BH(3) (1) by group 4 metallocene alkyne complexes of the type Cp(2)M(L)(η(2)-Me(3)SiC(2)SiMe(3)) [Cp = η(5)-cyclopentadienyl; M = Ti, no L (2Ti); M = Zr, L = pyridine (2Zr)] and group 4 metal amido complexes of the type M(NMe(2))(4) [M = Ti (8Ti), Zr (8Zr)] is presented.

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Titanocene(III) complexes with 2-phosphinoaryloxide ligands for the catalytic dehydrogenation of dimethylamine borane.

A study of the dehydrogenation of dimethylamine borane using different titanocene(III) complexes with 2-phosphinoaryloxide ligands is presented. Complexes Cp2Ti(κ(2)-O, P-O-C6H4-PR2) (3a: R = i-Pr, 3b: R = Ph) (Cp = η(5)-cyclopentadienyl) and Cp*2Ti(κ(1)-O-O-C6H4-PR2) (5a: R = i-Pr, 5b: R = Ph) (Cp* = η(5)-pentamethylcyclopentadienyl) were prepared by reactions of the 2-phosphinophenol ligand w...

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ژورنال

عنوان ژورنال: Environmental Health Perspectives

سال: 2006

ISSN: 0091-6765,1552-9924

DOI: 10.1289/ehp.114-a274a